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Lithium battery manufacturers analyze which lithium manganese battery and three kinds of lithium batteries are better

by:Vglory      2021-03-30
Lithium battery manufacturers analyze which lithium manganese battery and three kinds of lithium batteries are better? Lithium manganate batteries and ternary lithium batteries, as members of the lithium battery family, have their own advantages and disadvantages. In ternary lithium, lithium manganese acid and lithium iron phosphate three-power lithium battery systems, lithium manganese acid has obvious price advantages. With the increase of ternary materials in the field of power batteries, lithium manganate gradually exceeds the market share of lithium iron phosphate due to its high energy density. Lithium manganese acid battery: Lithium manganese acid battery has the advantages of good performance, convenient preparation and low cost. The disadvantage is that the solubility of manganese leads to poor high temperature performance and cycle performance. Through the doping of aluminum and sintering and granulation, the high temperature performance and cycle performance are greatly improved, which basically meets the actual use. In general, lithium manganese oxide batteries have low cost, strong stability, strong low-temperature performance, poor high-temperature performance, and a slightly faster decay rate. The spinel structure of lithium manganate and its two similar characteristics are very obvious, that is, both advantages and disadvantages are very prominent. Its advantages are: low temperature resistance, good multiplication performance, and relatively easy preparation. The disadvantages are: the material itself is unstable and needs to be mixed with other materials, with poor high temperature performance, poor cycle performance, and fast attenuation. These shortcomings of lithium manganate are due to the properties of manganese. However, due to the extensive supply of manganese, it has a significant cost advantage. Lithium manganese oxide is one of the promising anode materials for lithium-ion batteries. Compared with traditional anode materials, lithium cobalt oxide is rich in resources such as lithium manganese oxide. , Low cost, no pollution, good safety, good performance and other advantages, it is an ideal power battery cathode material, but its poor blood circulation and electrochemical stability greatly limit its industrialization. Lithium battery manufacturers believe that if lithium manganese acid batteries can maintain their original advantages, and through technological innovation, increase the number of cycles, increase capacity, and improve high and low temperature performance, it will occupy a place in the new energy segment. There are three types of lithium manganese oxide: 1. Layered lithium manganese oxide LiMnO2, theoretical capacity 285MA-H/g, voltage platform 4V. The layered structure is difficult to synthesize and is unstable. Li2Mn204 spinel structure is easy to produce, resulting in a drop in voltage plateau, poor stability, and irreversible capacity degradation. 2. High voltage spinel lithium manganese oxide LiMn204, theoretical capacity 148MA-H/g, voltage plateau 4.15. The high temperature performance is poor, and the capacity attenuation above 55℃ is serious. It is also prone to produce Li2Mn204 spinel structure, resulting in a drop in platform voltage, poor stability, and irreversible capacity degradation. This is the current industrial use of manganate crucian carp. 3. Spinel lithium manganese oxide Li2Mn2O4, low voltage (3V), small number of customers, poor circulation, is studying how to avoid producing this kind of thing. Ternary lithium battery: Ternary lithium battery has high energy density and cycle performance is better than ordinary lithium borate battery. At present, with the continuous improvement of the formula and structure, the nominal voltage of the battery has reached 3.7V, and the capacity has reached or exceeded the level of the lithium diamond battery. Ternary material power lithium batteries mainly include nickel diamond lithium aluminate batteries, lithium nickel diamond manganese batteries, and other high-temperature structures that are unstable, resulting in poor safety. High temperature and high pH can easily expand a single gas and cause failure, under current conditions The cost is not low. The advantages of ternary lithium batteries are: small size, high capacity density, low temperature resistance, and good cycle performance. They are the mainstream of new energy passenger cars. Disadvantages: poor thermal stability, decomposition occurs at a high temperature of 250-300 ℃, and the chemical reactions of the three lithium materials are particularly strong. Once oxygen molecules are released, they will burn rapidly under the action of high-temperature electrolyte, and then deflagration. There are many types of lithium-ion battery cathode materials, including lithium cobalt acid, lithium manganese acid, lithium nickel acid, lithium ternary materials, lithium iron phosphate, and so on. This ternary material combines the advantages of lithium cobalt acid, lithium nickel acid and lithium manganese acid, and has a certain practical value statement: The articles published on this site are all from the Internet and do not represent the views of this site. If there is any infringement, please contact Delete WeChat: Disclaimer: Some pictures and content of articles published on this site are from the Internet. If there is any infringement, please contact to delete the previous article: The energy storage industry is developing rapidly. Where is the breakthrough in the future?
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